Senyawa Toksik Pencemar Udara: Polycyclic Aromatic Hydrocarbons (PAHs)

NIA YUNIARTI HASAN

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Abstrak


Polycyclic Aromatic Hydrocarbons (PAHs) merupakan kelompok senyawa bersifat karsinogenik atau mutagenik, terutama benzo[a]pyrene. PAHs tersebar  melalui proses dispersi atmosfer, sehingga dapat ditemukan di daerah yang jauh dari sumbernya. Sumber PAHs antara lain emisi batu bara, produksi aluminium, pemanas rumah, kegiatan memasak, kendaraan bermotor, kebakaran hutan, pembangkit listrik batubara dan pembakaran sampah. Deposisi kering, deposisi basah dan penguapan dari air serta tanah merupakan  proses pertukaran PAHs udara, air, udara dan tanah. Paparan PAHs pada manusia terjadi melalui pernafasan, mulut dan penyerapan kulit. PAHs pada partikel-partikel udara kurang dari 10 µm (PM10) dapat terhirup dan selanjutnya terakumulasi pada sistem pernapasan manusia, sehingga menyebabkan gangguan kesehatan manusia. Baku mutu udara ambien senyawa toksik PAHs perlu ditetapkan untuk melindungi kesehatan masyarakat.


Kata kunci: benzo[a]pyrene, karsinogenik, deposisi

 

Abstract

Polycyclic Aromatic Hydrocarbons (PAHs) are a group of carcinogenic or mutagenic compounds, especially benzo[a]pyrene. PAHs are dispersed by atmospheric processes and found in the receptor area far from their sources. Coal emissions, aluminum production, home heating, cooking activities, motor vehicles, forest fires, coal-fired power plants and waste burning generate PAH emission. Meanwhile, PAHs exchanging process in air, water and soil occurs due to dry deposition, wet deposition and evaporation of water and soil.  PAHs exposure to human body have several pathways  through inhalation, ingestion and skin contact. PAHs in airborne particles of less than 10 µm (PM10) can be inhaled, subsequently accumulated in the human respiratory system, and cause human health problems. Ambient air quality standards for PAHs toxic compounds have to be established to protect public health.

Keywords: benzo[a]pyrene, carcinogenic, deposition



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http://www.inchem.org/documents/ehc/ehc/ehc202.htm

Abdel-Shafy H.I,dan Mansour M.S.M. (2016). A review on polycyclic aromatic hydrocarbons: Source, environmental impact, effect on human health and remediation. Egyptian Journal of Petroleum, 25, 107-123.

Agency for Toxic Substances and Disease Registry (ATSDR). (1990). Public Health Statement, Polycyclic Aromatic Hydrocarbons, December 1990. U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA. December 1990.

Agency for Toxic Substances and Disease Registry (ATSDR). (1995). Toxicological Profile for Polycyclic Aromatic Hydrocarbons, August 1995. U.S. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA, August 1995

Alberta Environment. (2004). Review of approaches for setting an objective for mixtures in ambient air using polycyclic aromatic hydrocarbons (PAHs) as an example: Benzo[a]pyrene.

Bi, X., Sheng, G., Peng, P., Chen, Y., Zhang, Z., Fu, J. (2003). Distribution of particulate and vapor-phase n-alkanes and polycyclic aromatic hydrocarbons in urban atmosphere of Guangzhou, China. Atmos. Environ. 37, 289–298.

Bi, X., Luo, W., Gaoa, J., Xua, L., Guo J., Zhang Q., Romesh, K.Y.,Giesy, J.P., Shichang Kang, S., Boer, J. (2016).Polycyclic aromatic hydrocarbons in soils from the Central-Himalayaregion: Distribution, sources, and risks to humans and wildlifeScience of the Total Environment 556, 12–22

Bidleman, T. F.(1988). Atmospheric Processes. Environ. Sci. Technol, 22, 361-367.

Bin L.L., Yan L., Ming L.J., Ning T., Kazuichi H., Tsunaeki M. (2007). Development of analytical methods for polycyclic aromatic hydrocarbons (PAHs) in air particulates : A review. Journal of Environmental Sciences 19, 1-11.

Callén, M.S.,López, J.M., Iturmendi, A., Mastral, A.M. (2012). Nature and sources of particle associated polycyclic aromatic hydrocarbons (PAH)in the atmospheric environment of an urban area. Environmental Pollution, 1-9.

Chen S,J., Jian W.J., Huang Y.C. (2001). PAHs and aerosol carbon in the exhaust of a gasoline powered engine. Aerosol and Air Quality Research Vol.1 No. 1., p 57 – 67

EPA. (1998). Locating and Estimating Air Emission from Sources of Polysiclic Aromatic Matter. United States Environmental Agency 454/R-98-014.

Environmental Protection Agency (EPA). (1999). Determination of polycyclic aromatic hydrocarbons (PAHs) in ambientair using gas chromatography/mass spectrometry (GC/MS). Second Edition Compendium Method TO-13A.

Environmental Protection Agency (EPA). (2008).Ambient Air Quality and Cleaner Air for Europe (CAFE) Directive (2008/50/EC). https://www.epa.ie/air/quality/standards/.

Gaga E.O. (2004). Investigation of Polycyclic Aromatic Hydrocarbon (PAH) Deposition in Ankara. The Middle East Technical University.

Giri S.K., Kumar A., Kumar A., Gulati S. (2016). Effects of Polycyclic Aromatic Hydrocarbons on Environment Health. https://www.researchgate.net/publication/301888451.

Golomb, D., Ryan D., Underhill, J., Wade, T., dan S. Zemba, S. (1997). Atmospheric deposition of toxics onto Massachusetts Bay II Polycyclic Aromatic Hydrocarbons. Armosphenc Enutronmenr 31 (9), 1361-1368.

Hall, D.E., Doel, R., Jorgensen, R., King, D.J., N. Mann, N., Scorlett, P. (1998). Polycyclic aromatic hydrocarbons in automotive exhaust emissions and fuel. CONCAWE.

Hanedar A., Alp K., Kaynak B., Baek J., Avsar E., Odman M.T. (2011). Concentrations and sources of PAHs at three stations in Istanbul, Turkey. Atmospheric Research 99, 391–399

Harner, T., Bidleman, T.F., (1998). Octanol-air partition coefficientfor describing particle/gas partitioning of aromaticcompounds in urban air. Environmental Science and Technology32, 1494–1502.

Hein, M., dan Kaiser, M. (2012). Environmental Control and Emission Reduction for Coking Plants. Air Pollution - A Comprehensive.Air Pollution: A Comprehensive Perspective.

Liu F., Xu Y., Liu J., Liu D., Li J., Zhang G., Li X., Zou S., Lai S. (2013). Atmospheric deposition of polycyclic aromatic hydrocarbons (PAHs) to a coastal site of Hong Kong, South China. Journal Atmospheric Environment 69 : p 265-272.

Lodovici, M., Venturini, M., Marini, E., Grechi, D., Dolara, P. (2003). Polycyclic aromatic hydrocarbons air levels in Florence, Italy, and their correlation with other air pollutants. Chemosphere 50, 377–382.

Ma, W.L., Li, Y.-F., Qi, H., Sun, D.Z., Liu, L.Y., dan Wang, D.-G. (2010). Seasonal variations of sources of polycyclic aromatic hydrocarbons (PAHs) to a northeastern urban city, China. Chemosphere, 79(4), 441–447.

Maliszewska B., Kordybach. (1999). Sources, Concentations, fate and effects of Polycyclic Aromatic Hydrocarbons (PAHs) in The Environment Part A : PAHs in Air. Polish of Journal of Environmental Studies Volume 8 No. 3, p 131-136.

Mackay, D., Wan-Ying Shiu and K.C. Ma. 1995. Illustrated Handbook of Physical-Chemical Properties and Environmental Fate of Organic Chemicals. Vol. 4. Lewis Publishers, Boca Raton, FL.

Marr, L.C., Dzepina, K., Jimenez, J.L., Reisen, F., Bethel, H.L., Arey, J., Gaffney, J.S.,Marley, N.A., Molina, L.T., Molina, M.J., 2006. Sources and transformations ofparticle-bound polycyclic aromatic hydrocarbons in Mexico City. AtmosphericChemistry and Physics 6, 1733-1745

Munawir K. (2007). Kadar Polisiklik Aromatik Hidrokarbon (PAH) dalam air di Teluk Klabat. Oseanologi dan Limnologi di Indonesia Volume 33 (3).

Menzie C.A., Potocki B.B., Santodonato J. Exposure to carcinogenic PAHs in the environment, Environm. Sci. Technol. 26, 1278, 1992.

Mo, Z., Wang, Z., Mao, G., Pan, X., Wu, L., Xu, P., Chen, S., Wang, A., Zhang, Y., Luo, J., Ye, X., Wang, X.,Chen, Z., danLou, X. (2019). Characterization and healthrisk assessment of PM2.5-boundpolycyclic aromatic hydrocarbons in5 urban cities of Zhejiang Province,China. Scientific Reports9, Article number: 7296.

Niu, J., Sun, P., Schramm, K.-W., 2007. Photolysis of polycyclic aromatic hydrocarbonsassociated with fly ash particles under simulated sunlight irradiation.Journal of Photochemistry and Photobiology 186, 93-98.

Pitts B.J.F., Pitts J.JN. (1986). Atmospheric Cemistry Fundamentals and Experimental Techniques. A Wiley-Interscience Publication John Wiley & Sons.

Prakash B.O. (2019). Persistent organic compounds in the environment their impact on human health: A review. GSC Biological and Pharmaceutical Sciences, 08(02), 081–088.

Raja, S., Valsaraj, K.T., 2006. On the reactive uptake of gaseous PAH molecules bymicron-sized atmospheric water droplet. Atmospheric Research 81, 277-292.

Ravindra K., Sokhi R., Grieken R.V. (2008). Atmospheric olysiclic Aromatic Hydrocarbons : Source Attribution, Emission Factors and Regulation. Atmospheric Environment.

Rubailo, A.I., Oberenko, A.V. (2008). Polycyclic Aromatic Hydrocarbons as Priority Pollutants. Journal of Siberian Federal University. Chemistry, 4, 344-354

Seinfeld, John H, pandis S.N. (1998). Atmospheric Chemistry and Physics from Air Pollution to Climate Change, John Wiley and Son, Inc., New York.

Shubhankar B., Ambade B. (2016). A review on deposition of Polycyclic Aromatic Hydrocarbons in different environmental matrix and study its toxicity and carcinogenic effect. Asian Journal of Chemistry, 28 (11), 2341 - 234.

Thai, P.K., Li, Z., Andreas Sjödin, A., Fox,A., Diep, N.B., Binh,T.T., dan Mueller, J.F. (2015). Biomonitoring of polycyclic aromatic hydrocarbons exposure in small groups of residents in Brisbane, Australia and Hanoi, Vietnam, and those travelling between the two cities. Chemosphere, 139, 358–364.

Tucker, S.A., Griffin, J.M., dan Acree, W.E.Jr. (1994). Selective Fluorescence Quenching to Discriminate Between Alternant and Non alternant Polycyclic Aromatic Hydrocarbons: Acephenanthrylene Derivatives as Except ions to the Nitromethane Quenching Rule. Analyst 11 (90), 2129-2133.

Tobiszewski M., Namiesnik J. (2012). Review : PAH diagnostic ratios for the identification of pollution emission sources. Environmental Pollution 162, 110-119.

United States Environmental Protection Agency. (2008). Polycyclic Aromatic Hydrocarbons (PAHs).

Uthe, J.F. (1991). Polycyclic aromatic hydrocarbon in the environment. Marine Chemistry Division, Departement of Fisher and Ocenas.Halifax.Canadian chemical news : 25-27.

Wild S.R., Jones K.C. (1995). Polynuclear aromatic hydrocarbons in the United Kingdom environment : a preliminary source inventory and budget. Environment Pllution 88, 91.

Wiriya W., Papamontol T., Chantara S. (2013). PM10-bound polycyclic aromatic hydrocarbons in Chiang Mai (Thailand): Seasonal variations, source identification, health risk assessment and their relationship to air-mass movement. Atmospheric Research 124,109-122.

World Health Organization, (2000). WHO Guidelines for Indoor Air Quality: Selected Pollutants.




DOI: https://doi.org/10.26760/rekalingkungan.v8i2.67-77

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